ANODIC-OXIDATION OF BENZYL ALCOHOL TO BENZALDEHYDE USING HYDROQUINONE AS MEDIATOR IN NONSOLVENT SYSTEM

被引：3

作者：

CHEN, LM

CHEN, YL

CHOU, TC

机构：

来源：

DENKI KAGAKU | 1994年 / 62卷 / 12期

关键词：

HYDROQUINONE; BENZYL ALCOHOL; BENZALDEHYDE; NONSOLVENT SYSTEM;

D O I：

10.5796/electrochemistry.62.1173

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

In this study, an electrochemical synthesis system in non-solvent system was systematically studied including cyclic voltammograms, IE curves, current efficiency and yield. Hydroquinone is a practical redox mediator in this system. The yield of benzaldehyde at a fixed potential is twice of that without hydroquinone as the mediator in the non-solvent system. Effect of solvent has also been examined to compare with the non-solvent system. The addition of acetonitrile as solvent can increase the yield but reduce the current efficiency.

引用

页码：1173 / 1178

页数：6

共 9 条

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