SYNTHESIS OF A RHENIUM COMPLEX APPENDING A CYCLODEXTRIN UNIT ON A LIGAND

被引：14

作者：

NAKAMURA, A

OKUTSU, S

ODA, Y

UENO, A

TODA, F

机构：

[1] Department of Bioengineering, Faculty of Bioscience and Biotechnology, Tokyo Institute of Technology, Midori-ku, Yokohama, 227

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 39期

关键词：

RHENIUM COMPLEX; CYCLODEXTRIN; INCLUSION; SUPRAMOLECULE; ELECTRON TRANSFER;

D O I：

10.1016/0040-4039(94)85371-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A supramolecular species has been designed for studying the mechanism of long-range electron transfer through non-covalent bonding. A rhenium complex with a cyclodextrin unit on the side arm of a ligand has been synthesized. The rhenium complex trapped N,N-dicthylanilline into its cavity, and the luminescence from the host complex was quenched by the guest.

引用

页码：7241 / 7244

页数：4

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