CYCLIC POLYSILANES .14. HOMOLOGOUS SERIES OF CYCLIC POLYSILANES FROM (ME2SI)5 TO (ME2SI)35

被引：16

作者：

BROUGH, LF

MATSUMURA, K

WEST, R

机构：

[1] Department of Chemistry, University of Wisconsin, Madison, Wisconsin

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 12期

关键词：

D O I：

10.1002/anie.197909551

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Permethylsilicon rings having 5 through 35 members arise on slow addition of Me2SiCl2 to Na/K alloy in boiling tetrahydrofuran. After removal of the major products (Me2Si)5 and (Me2Si)6 (recrystallization and fractional sublimation) the cyclic polysilanes can be detected by high pressure liquid chromatography. Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：955 / 956

页数：2

共 11 条

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