A MIXED-VALENT PENTANUCLEAR GOLD COMPLEX CONTAINING A LINEAR AU5(9)+ CHAIN

被引：37

作者：

USON, R ^{[1
]}

LAGUNA, A ^{[1
]}

LAGUNA, M ^{[1
]}

JIMENEZ, J ^{[1
]}

JONES, PG ^{[1
]}

机构：

[1] TECH UNIV BRAUNSCHWEIG,INST ANORGAN & ANALYT CHEM,W-3300 BRAUNSCHWEIG,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 02期

关键词：

D O I：

10.1002/anie.199101981

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An unprecedented Au5 chain 3, in which the most likely distribution of oxidation states is Au(II)-Au(II)-Au(I)-Au(II)-Au(II), forms unexpectedly from the gold complexes 1 and 2 according to the equation (a). All gold atoms of the cation of 3 have square-planar coordination, R = C6F5.

引用

页码：198 / 199

页数：2

共 2 条

[1] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURES OF [AU(CH2)2PPH2]2(CF3)2, [AU(CH2)2PPH2]2(C6F5)2, AND [PPN][AU(C6F5)4] - 2 DINUCLEAR GOLD(II) YLIDE COMPLEXES CONTAINING ALKYL AND ARYL LIGANDS AND A TETRAKIS(PENTAFLUOROPHENYL)AURATE(III) ANION COMPLEX [J].

MURRAY, HH ;

FACKLER, JP ;

PORTER, LC ;

BRIGGS, DA ;

GUERRA, MA ;

LAGOW, RJ .

INORGANIC CHEMISTRY, 1987, 26 (03) :357-363

[2] THE 1ST EXAMPLE OF A DIRECT FORMAL GOLD(I)-GOLD(III) BOND - SYNTHESIS AND STRUCTURE OF [(AU(CH2)2PPH2)2AU(C6F5)3] [J].

USON, R ;

LAGUNA, A ;

LAGUNA, M ;

TARTON, MT ;

JONES, PG .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (11) :740-741

← 1 →