ADDITION-COMPOUNDS OF NUCLEOPHILES AND 3-ETHYLTHIO-6-OXO-6H-1,2-DITHIOLO[4,3-C]1,2-DITHIOLIUM TETRAFLUOROBORATE - SYNTHESIS OF 3H,6H-1,2-DITHIOLO[4,3-C]1,2-DITHIOLE-3-ONE-6-THIONE

被引：6

作者：

KORDTS, B ^{[1
]}

RICHTER, AM ^{[1
]}

FANGHANEL, E ^{[1
]}

机构：

[1] TH CARL SCHORLEMMER LEUNA MERSEBURG,SEKT CHEM,OTTO NUSCHKE STR,O-4200 MERSEBURG,GERMANY

来源：

MONATSHEFTE FUR CHEMIE | 1991年 / 122卷 / 1-2期

关键词：

3H,6H-1,2-DITHIOLO[4,3-C]1,2-DITHIOLE-3,6-DITHIONE,; SYNTHESIS AND PARTIAL DESULFURATION OF; 3H,6H-1,2-DITHIOLO[4,3-C]1,2-DITHIOLE-3-ONE-6-THIONE,; SYNTHESIS AND ALKYLATION OF; 3-ETHYLTHIO-6-OXO-6H-1,2-DITHIOLO[4,3-C]1,2-DITHIOLIUM; TETRAFLUOROBORATE; SYNTHESIS AND FORMATION OF ADDUCTS WITH; NUCLEOPHILES OF;

D O I：

10.1007/BF00815167

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A smooth method of synthesizing 3H, 6H-1,2-dithiolo[4,3-c]1,2-dithiole-3,6-dithione (3), and also its partial desulfuration to yield 3H, 6H-1,2-dithiolo[4,3-c]1,2-dithiole-3-one-6-thione (4) is presented. The ethylation product 5 of the monothione 4 reacts with various nucleophilic reagents to form remarkably stable adducts. The adducts of 5 with methanol, tert-butyl mercaptan, and with aniline could be isolated and characterized by their H-1-NMR spectra.

引用

页码：71 / 75

页数：5

共 12 条

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