SYNTHESIS AND REACTIONS OF DIAZOACETYL CHLORIDE - DETECTION OF DIAZOKETENE

被引：10

作者：

BESTMANN, HJ

SOLIMAN, FM

机构：

[1] Institut für Organische Chemie, Universität Erlangen-Nürnberg, Erlangen, D-8520

[2] National Research Center Dokki, Cairo

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 12期

关键词：

D O I：

10.1002/anie.197909471

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of phosgene with diazomethane in the molar ratio 1:2 permitted the first synthesis of diazoacetyl chloride (3). Compound 3 decomposes only slowly below 0°C and is an excellent diazoacetylation reagent. The long‐sought diazoketene N2CCO could be generated in solution from 3 and diazbicyclooctane. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：947 / 948

页数：2