DIFFUSION-CONTROLLED INTERMOLECULAR ELECTRON-TRANSFER STUDIED BY TRANSIENT ABSORPTION AND DEGENERATE 4-WAVE-MIXING MEASUREMENTS

被引：2

作者：

ASSEL, M

HOFER, T

LAUBEREAU, A

KAISER, W

机构：

[1] Physik Department E 11, Technische Universität München

来源：

CHEMICAL PHYSICS LETTERS | 1995年 / 234卷 / 1-3期

关键词：

D O I：

10.1016/0009-2614(95)00027-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The time dependence of intermolecular electron transfer kinetics is studied by two experimental techniques: transient absorption measurements and degenerate four-wave mixing after excitation of the donor molecules by picosecond UV pulses. In the system perylene/phthalic anhydride the electron transfer rate depends strongly on the concentration of the acceptor molecule phthalic anhydride. The value agrees with theoretical calculations based on a diffusion-controlled process.

引用

页码：151 / 158

页数：8

共 19 条

[1]

[Anonymous], 1970, PHOTOPHYSICS AROMATI

[2] RELATIONS BETWEEN FLUORESCENCE AND ABSORPTION PROPERTIES OF ORGANIC MOLECULES [J].