STERIC EFFECTS IN HETEROBORANES .3. 1-PH-2-ME-1,2-CLOSO-C2B10H10

被引：23

作者：

MCGRATH, TD ^{[1
]}

WELCH, AJ ^{[1
]}

机构：

[1] HERIOT WATT UNIV,DEPT CHEM,EDINBURGH EH14 4AS,MIDLOTHIAN,SCOTLAND

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷

关键词：

D O I：

10.1107/S0108270194005809

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystallographically determined structure of 2-methyl-1-phenyl-1,2-dicarba-cIoso-dodecaborane(12), C9H18B10, is reported. The 12-vertex polyhedron is relatively undistorted although the phenyl substituent is twisted by ca 73 degrees from its electronically preferred orientation by steric pressure from the methyl group, resulting in a C-C(cage) separation of 1.695 (5) Angstrom.

引用

页码：646 / 649

页数：4

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