NICKEL(0)-INDUCED SYNTHESIS OF ETHYLLITHIUM FROM LITHIUM, HYDROGEN, AND ETHYLENE

被引：12

作者：

JONAS, K

PORSCHKE, KR

机构：

[1] Max-Planck-Institut für Kohlenforschung, Mülheim-Ruhr, D-4330

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 06期

关键词：

D O I：

10.1002/anie.197904881

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Lithium‐nickel(0) system often prove surprising: thus (COD)2Ni and Li react together in tetrahydrofuran to give (COD)2NiLi2(THF)4, which can be reduced by H2 under normal pressure to form the new “lithium hydride” 1. Unlike LiH, 1 adds to CC double bonds; it forms C2H5Li with ethylene. (Formula Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：488 / 489

页数：2

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