SYNTHESIS AND DIMERIZATION OF BICYCLO [4.4.1]UNDEC-1 (11)-ENE, A BRIDGED TRANS-CYCLOHEPTENE

被引：19

作者：

BECKER, KB

CHAPPUIS, JL

机构：

[1] Institut für Organische Chemie, Universität Basel, Basel, CH-4056

来源：

HELVETICA CHIMICA ACTA | 1979年 / 62卷 / 01期

关键词：

D O I：

10.1002/hlca.19790620106

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of bicyclo [4.4.1] undec‐1 (11)‐ene (5) by intramolecular Wittig reaction is described. The Bredt olefin could not be isolated, but dimerized rapidly to a novel compound 15 containing a cyclopropane ring. The olefin 5 was trapped in situ by 2,5‐diphenylbenzo [c]furan. Copyright © 1979 Verlag GmbH & Co. KGaA, Weinheim

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页码：34 / 43

页数：10

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