CRYSTALLIZATION KINETICS OF WATER BELOW 150 K

被引：105

作者：

HAGE, W ^{[1
]}

HALLBRUCKER, A ^{[1
]}

MAYER, E ^{[1
]}

JOHARI, GP ^{[1
]}

机构：

[1] MCMASTER UNIV, DEPT MAT SCI & ENGN, HAMILTON L8S 4L7, ON, CANADA

来源：

JOURNAL OF CHEMICAL PHYSICS | 1994年 / 100卷 / 04期

关键词：

D O I：

10.1063/1.466468

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Metastable liquid water, obtained by heating its hyperquenched glassy state above its glass --> liquid transition temperature, crystallizes to cubic ice. Kinetics of this crystallization has been studied by Fourier transform infrared spectroscopy by determining the change in the spectra of stretching vibrations of the decoupled OD oscillator in 3.6 mole % HOD in H2O. The crystallization kinetics follows the equation x=[1-exp(-kt(n))] and is diffusion controlled. Annealing at a temperature below its glass-->liquid transition temperature alters this kinetics as the grain-growth process begins to control the early stages of crystallization.

引用

页码：2743 / 2747

页数：5

共 17 条

[1] HEAT-CAPACITY OF WATER AT EXTREMES OF SUPERCOOLING AND SUPERHEATING [J].

ANGELL, CA ;

OGUNI, M ;

SICHINA, WJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1982, 86 (06) :998-1002

[2] Granulation, Phase Change, and Microstructure - Kinetics of Phase Change. III [J].

Avrami, M .

JOURNAL OF CHEMICAL PHYSICS, 1941, 9 (02) :177-184

[3] Kinetics of phase change I - General theory [J].

Avrami, M .

JOURNAL OF CHEMICAL PHYSICS, 1939, 7 (12) :1103-1112

[4]

Avrami M., 1940, J CHEM PHYS, V8, P212, DOI DOI 10.1063/1.1750631

[5]

DOREMUS RH, 1985, RATES PHASE TRANSFOR, pCH2

[6] TEMPERATURE CALIBRATION OF LOW-TEMPERATURE INFRARED CELLS [J].

FORD, TA ;

SETO, PF ;

FALK, M .

SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY, 1969, A 25 (09) :1650-&

[7] CALORIMETRIC STUDY OF THE VITRIFIED LIQUID WATER TO CUBIC ICE PHASE-TRANSITION [J].

HALLBRUCKER, A ;

MAYER, E .

JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (03) :503-505

[8] THE HEAT-CAPACITY AND GLASS-TRANSITION OF HYPERQUENCHED GLASSY WATER [J].

HALLBRUCKER, A ;

MAYER, E ;

JOHARI, GP .

PHILOSOPHICAL MAGAZINE B-PHYSICS OF CONDENSED MATTER STATISTICAL MECHANICS ELECTRONIC OPTICAL AND MAGNETIC PROPERTIES, 1989, 60 (02) :179-187

[9] THE GLASS LIQUID TRANSITION OF HYPERQUENCHED WATER [J].

JOHARI, GP ;

HALLBRUCKER, A ;

MAYER, E .

NATURE, 1987, 330 (6148) :552-553

[10]

Johnson WA, 1939, T AM I MIN MET ENG, V135, P416

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