PALLADIUM-CATALYZED ARYLATION OF ALLYLIC DIOLS - HIGHLY SELECTIVE SYNTHESIS OF PHENYL-SUBSTITUTED ALLYLIC DIOLS

被引：48

作者：

KANG, SK

JUNG, KY

PARK, CH

NAMKOONG, EY

KIM, TH

机构：

[1] Department of Chemistry, Sung Kyun Kwan University, Suwon, 440-746, Natural Science Campus

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 35期

关键词：

D O I：

10.1016/0040-4039(95)01294-R

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The coupling reaction of iodobenzene with allylic diols in the presence of Pd(OAc)(2) and nBu(3)P as catalysts using K2CO3 as base afforded the phenyl-substituted allylic diols. However, under the same reaction conditions with Et(3)N as base, phenyl-substituted alpha-hydroxy ketone was obtained.

引用

页码：6287 / 6290

页数：4

共 14 条

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[7] PALLADIUM-CATALYZED REACTION OF VINYLIC HALIDES WITH ALLYLIC ALCOHOLS - A HIGHLY CHEMOCONTROLLED, REGIOCONTROLLED AND STEREOCONTROLLED SYNTHESIS OF CONJUGATED DIENOLS
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[9] PALLADIUM-CATALYZED ARYLATION OF ALLYLIC ALCOHOLS - HIGHLY SELECTIVE SYNTHESIS OF BETA-AROMATIC CARBONYL-COMPOUNDS OR BETA-AROMATIC ALPHA,BETA-UNSATURATED ALCOHOLS
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