The vibrational constants of the ground states of H2+HD+ and D-2(+) from photoelectron spectroscopic measurements

被引:5
作者
Cornford, A. B. [1 ]
Frost, D. C. [1 ]
McDowell, C. A. [1 ]
Ragle, J. L. [1 ]
Stenhouse, I. A. [1 ]
机构
[1] Univ British Columbia, Dept Chem, Vancouver 8, BC, Canada
关键词
D O I
10.1016/0009-2614(70)85115-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The 584 angstrom photoelectron spectra of H-2(+), HD+ and D-2(+) allow the vibrational intervals in the (2)Sigma(perpendicular to)(g) states of these ions to be measured, and so the vibrational constants omega(e) and omega(e)x(e) can be derived. These new experimental values are compared with previous theoretical calculations.
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页码:486 / 488
页数:3
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