STRUCTURE OF AN OXAZIRCONACYCLOHEXADIENE SYNTHESIZED BY THERMOLYSIS OF DIFURYLZIRCONOCENE

被引：9

作者：

ERKER, G ^{[1
]}

PETRENZ, R ^{[1
]}

KRUGER, C ^{[1
]}

NOLTE, M ^{[1
]}

机构：

[1] MAX PLANCK INST COAL RES,W-4330 MULHEIM,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 431卷 / 03期

关键词：

D O I：

10.1016/0022-328X(92)83334-E

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thermolysis of bis(2-furyl)zirconocene 1 at 185-degrees-C gives 1,1-bis(eta-cyclopentadienyl)-1-zircona-2-oxa-6-(2'-furyl)cyclohexa-3,5-diene 2 via a coupled sigma,sigma-exchange reaction. Complex 2 was characterized by X-ray diffraction and shown to be monomeric in the crystal and to have a non-planar twist-like oxametallacyclohexadiene ring conformation.

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页码：297 / 302

页数：6

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