SYNTHESIS OF MIXED-RING ORGANOACTINIDE COMPLEXES .2. (C8H8)(C5ME5)U(THF) AND ITS 4,4'-DIMETHYL-2,2'-BIPYRIDINE DERIVATIVE

被引：57

作者：

SCHAKE, AR

AVENS, LR

BURNS, CJ

CLARK, DL

SATTELBERGER, AP

SMITH, WH

机构：

[1] LOS ALAMOS NATL LAB,DIV ISOTOPE & NUCL CHEM,LOS ALAMOS,NM 87545

[2] LOS ALAMOS NATL LAB,DIV NUCL MAT TECHNOL,LOS ALAMOS,NM 87545

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 05期

关键词：

D O I：

10.1021/om00029a004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The (pentamethylcyclopentadienyl)uranium-(III) complex (C5Me5)UI2(THF)3 reacts with K2C8H8 in THF to form the mixed-ring uranium(III) complex (C8H8)(C5Me5)U(THF) (1). Treatment of 1 with 4,4'-dimethyl-2,2'-bipyridine (Me2bpy) gives the 10-coordinate complex (C8H8)(C5Me5)U(Me2bPY) (2). The syntheses of 1 and 2 and the X-ray structure of 2 are described herein.

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页码：1497 / 1498

页数：2

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