SYNTHESIS AND PROPERTIES OF BIS[OXYBIS(METHYLENETHIO)]TETRATHIAFULVALENE AND ITS SULFUR ANALOG - PI-DONORS FOR ORGANIC METALS

被引：7

作者：

MULLER, H ^{[1
]}

UEBA, Y ^{[1
]}

机构：

[1] SUMITOMO ELECT IND, R&D GRP, 1-1-3 SHIMAYA, KONOHANA KU, OSAKA 554, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1993年 / 66卷 / 06期

关键词：

D O I：

10.1246/bcsj.66.1773

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bis[oxybis(methylenethio)]tetrathiafulvalene (BOBMT- TTF) and bis[thiobis(methylenethio)]-tetrathiafulvalene (BTBMT-TTF) were synthesized in two steps starting from 1,3,4,6-tetrathiapentalene-2,5-dione. The electrochemical and donor of both compounds are discussed. BOBMT-TTF forms a highly conducting charge transfer complex with TCNQ (sigma(RT) is-approximately-equal-to 10 S cm-1).

引用

页码：1773 / 1777

页数：5

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