THE CN STRETCH OF HEXACYANOMETALLATES AS A SENSOR OF LIGAND OUTER CATION INTERACTIONS .1. FERRICYANIDES AND COBALTICYANIDES

被引：45

作者：

BERTRAN, JF

PASCUAL, JB

RUIZ, ER

机构：

[1] Centro Nacional de Investigaciones Científicas, La Habana,

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1990年 / 46卷 / 05期

关键词：

D O I：

10.1016/0584-8539(90)80023-R

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The CN frequencies of 39 hexacyanometallates (ferricyanides and cobalticyanides) are correlated with atomic parameters of the outer cation. Evidence is obtained of the presence of σ and π interactions in the bonding of the outer cation to the CN ligand. Quantitative estimation of the effect of these mechanisms on the shift of νCN is presented. © 1990.

引用

页码：685 / 689

页数：5

共 13 条

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