SYNTHESIS AND CHARACTERIZATION OF A NOVEL DIMER OF DI(MU-OXO)MANGANESE DIMERS WITH 2 COORDINATED WATER-MOLECULES IN (III,IV,III,IV) OXIDATION-STATE

被引：33

作者：

SUZUKI, M

HAYASHI, Y

MUNEZAWA, K

SUENAGA, M

SENDA, H

UEHARA, A

机构：

[1] KANAZAWA UNIV, FAC SCI, DEPT CHEM, KANAZAWA, ISHIKAWA 920, JAPAN

[2] KANAZAWA UNIV, COLL LIBERAL ARTS, DEPT CHEM, KANAZAWA, ISHIKAWA 920, JAPAN

来源：

CHEMISTRY LETTERS | 1991年 / 11期

关键词：

D O I：

10.1246/cl.1991.1929

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A dimer of di(mu-oxo)dimanganese(III,IV) dimers with two coordinated water molecules, [{Mn2(tmdp)(O)2(H2O)}2] (CF3SO3)4.6H2O, was prepared, where Htmdp is 1,5-bis[bis(2-pyridylmethyl)amino]-3-pentanol, and its crystal structure was determined by X-ray structure analysis. The complex cation consists of two di(mu-oxo)Mn2(III,IV) dimers which are linked by two tmdps to form a dimer of dimers with a bilayered structure.

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页码：1929 / 1932

页数：4

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