X-Ray Crystal Structure of Hexakis(dimethylamino)dimolybdenum. A New Compound with a Metal-to-metal Triple Bond

被引：35

作者：

Chisholm, Malcolm ^{[2
]}

Cotton, F. Albert ^{[1
]}

Frenz, Bertram A. ^{[1
]}

Shive, Larry ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

[2] Princeton Univ, Dept Chem, Princeton, NJ 08540 USA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1974年 / 12期

关键词：

D O I：

10.1039/c39740000480

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The compound Mo2(NMe2)(6) is shown by X-ray crystallography to contain centrosymmetric molecules (virtual symmetry S-6, differing little from D-3d) with a triple bond between the metal atoms [Mo-Mo = 2.214(2)]

引用

页码：480 / U19

页数：2

共 8 条

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[5] NEW CLASS OF BINUCLEAR RHENIUM(II) HALIDE SPECIES CONTAINING A STRONG METAL-METAL BOND - CHEMISTRY AND STRUCTURE OF COMPLEXES OF TYPE RE2X4(PR3)4
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[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1974, (01) : 4 - 5
[6] STRONG HOMONUCLEAR METAL-METAL BONDS
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[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1969, 2 (08) : 240 - &
[7] HUQ F, 1971, CHEM COMMUN, P1070
[8] X-RAY CRYSTAL-STRUCTURE OF DICARBONYLPENTAMETHYLCYCLOPENTADIENYLCHROMIUM DIMER
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[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1972, (24) : 1333 - 1334

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