S-N COMPOUNDS AS DELAYED ACTION CHEMICALS IN VULCANIZATION

被引：41

作者：

MORITA, E

机构：

来源：

RUBBER CHEMISTRY AND TECHNOLOGY | 1980年 / 53卷 / 03期

关键词：

PREVULCANIZING INHIBITORS - VULCANIZATION ACCELERATORS - VULCANIZING AGENTS;

D O I：

10.5254/1.3535050

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This bibliography-based review-paper covers the development of S-N (organic compounds with sulfur-nitrogen bonds) compounds as delayed action chemicals for vulcanizing rubber, the various structural types, properties, applications, and the mechanism of their function during vulcanization. Vulcanization accelerators reviewed include: thiazolsulfonamides; thiocarbamylsulfenamides; phosphinothioylaminosulfides; triazine sulfenamide. Vulcanizing agents are: dithioamines; iminodithiothiazoles; aminothiocarbamyldisulfides. The following prevulcanization inhibitors are discussed: (1) S-N compounds as prevulcanization inhibitors (thioimide, cyclohexylthioamines, thiosulfonamides); (2) N-aminothioimide cure modifier; and (3) the mechanism of prevulcanization inhibition.

引用

页码：393 / 436

页数：44