NEW PHOTOCHEMICALLY LABILE PROTECTING GROUP FOR PHOSPHATES

被引：25

作者：

FURUTA, T ^{[1
]}

TORIGAI, H ^{[1
]}

OSAWA, T ^{[1
]}

IWAMURA, M ^{[1
]}

机构：

[1] TOHO UNIV, FAC SCI, DEPT BIOMOLEC SCI, 2-2-1 MIYAMA, FUNABASHI, CHIBA 274, JAPAN

来源：

CHEMISTRY LETTERS | 1993年 / 07期

关键词：

D O I：

10.1246/cl.1993.1179

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New photochemically labile phosphate protecting group was developed. These phosphate esters have high molar extinction coefficient (epsilon340 = 34500 dm3 mol-1 cm-1) and rapidly release parent phosphates upon irradiation (>300 nm) with high quantum efficiency for disappearance (phi(dis) = 0.22 at 340 nm).

引用

页码：1179 / 1182

页数：4

共 8 条

[1] SYNTHETIC, MECHANISTIC AND PHOTOCHEMICAL STUDIES OF PHOSPHATE-ESTERS OF SUBSTITUTED BENZOINS
CORRIE, JET
TRENTHAM, DR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1992, (18): : 2409 - 2417
[2] FURUTA T, UNPUB
[3] PHOTOCHEMISTRY OF PHOSPHATE-ESTERS - AN EFFICIENT METHOD FOR THE GENERATION OF ELECTROPHILES
GIVENS, RS
MATUSZEWSKI, B
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (22) : 6860 - 6861
[4] PHOTOCHEMISTRY OF ALPHA-KETO PHOSPHATE-ESTERS - PHOTORELEASE OF A CAGED CAMP
GIVENS, RS
ATHEY, PS
KUEPER, LW
MATUSZEWSKI, B
XUE, JY
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (22) : 8708 - 8710
[5] PHOTOCHEMISTRY OF PHOSPHATE-ESTERS
GIVENS, RS
KUEPER, LW
[J]. CHEMICAL REVIEWS, 1993, 93 (01) : 55 - 66
[6] LIGHT-FLASH PHYSIOLOGY WITH SYNTHETIC PHOTOSENSITIVE COMPOUNDS
GURNEY, AM
LESTER, HA
[J]. PHYSIOLOGICAL REVIEWS, 1987, 67 (02) : 583 - 617
[7] PHOTOLABILE 1-(2-NITROPHENYL)ETHYL PHOSPHATE-ESTERS OF ADENINE-NUCLEOTIDE ANALOGS - SYNTHESIS AND MECHANISM OF PHOTOLYSIS
WALKER, JW
REID, GP
MCCRAY, JA
TRENTHAM, DR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (21) : 7170 - 7177
[8] WOOTTON JF, 1988, PHOTOCHEMICAL PROBES, P277

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