AROMATICITY AND SUPERAROMATICITY IN CYCLOPOLYACENES

被引：59

作者：

AIHARA, J

机构：

[1] Department of Chemistry, Faculty of Science, Shizuoka University, Oya

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1994年 / 05期

关键词：

D O I：

10.1039/p29940000971

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The topological resonance energy (TRE) method has been applied to linear and zigzag isomers of cyclopolyacenes to investigate their aromatic character. In general, zigzag cyclopolyacenes are found to be highly aromatic. Every linear cyclopolyacene is much less aromatic than the zigzag isomer, and large linear and zigzag cyclopolyacenes are as aromatic as their respective polyacenes. A Huckel-like rule is observed for linear cyclopolyacenes. A super-ring structure scarcely affects the aromatic character of sizeable cyclopolyacenes.

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页码：971 / 974

页数：4

相关论文

共 31 条

[1] WHY AROMATIC-COMPOUNDS ARE STABLE [J].

AIHARA, J .

SCIENTIFIC AMERICAN, 1992, 266 (03) :62-68

[2] NEW DEFINITION OF DEWAR-TYPE RESONANCE ENERGIES [J].

AIHARA, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (10) :2750-2758

[3] RESONANCE ENERGIES OF POLYACENES AND RELATED COMPOUNDS [J].

AIHARA, J .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1975, 48 (12) :3637-3640

[4] GENERAL GRAPH-THEORY OF SUPERAROMATICITY [J].

AIHARA, J .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1993, 66 (01) :57-60

[5] IS SUPERAROMATICITY A FACT OR AN ARTIFACT - THE KEKULENE PROBLEM [J].

AIHARA, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (03) :865-868

[6] SPHERICAL AROMATICITY OF BUCKMINSTERFULLERENE [J].

AIHARA, J ;

HOSOYA, H .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1988, 61 (07) :2657-2659

[7] AROMATIC CHARACTER OF TYPICAL C-60 DERIVATIVES [J].

AIHARA, J ;

TAKATA, S .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1994, (01) :65-69

[8]

[Anonymous], 1972, AROMATIC SEXTET

[9] TOWARDS THE MAKING OF [12]COLLARENE [J].

ASHTON, PR ;

ISAACS, NS ;

KOHNKE, FH ;

SLAWIN, AMZ ;

SPENCER, CM ;

STODDART, JF ;

WILLIAMS, DJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (07) :966-969

[10] MOLECULAR BELTS .2. SUBSTRATE-DIRECTED SYNTHESES OF BELT-TYPE AND CAGE-TYPE STRUCTURES [J].

ASHTON, PR ;

GIRRESER, U ;

GIUFFRIDA, D ;

KOHNKE, FH ;

MATHIAS, JP ;

RAYMO, FM ;

SLAWIN, AMZ ;

STODDART, JF ;

WILLIAMS, DJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (13) :5422-5429

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