RADICAL IONS .26. RADICAL-ANIONS OF PERPHENYLCYCLOPOLYSILANES

被引：23

作者：

KIRA, M ^{[1
]}

BOCK, H ^{[1
]}

HENGGE, E ^{[1
]}

机构：

[1] TECH UNIV GRAZ,A-8010 GRAZ,AUSTRIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 164卷 / 03期

关键词：

D O I：

10.1016/S0022-328X(00)81691-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Perphenylcyclopolysilanes [Si(C6H5)2]n (n = 4, 5) are reduced by potassium to radical anions. Their simple ESR spectra demonstrate, that the extra electron is confined to the inner SinC2n skeleton of the uncleaved and presumably planarized cyclopolysilanes. © 1979.

引用

页码：277 / 280

页数：4

共 9 条

[1] CYCLIC POLYSILANES .10. GEOMETRICAL ISOMERS AND ELECTRONIC PROPERTIES OF 1,2,3,4-TETRA-T-BUTYLTETRAMETHYLCYCLOTETRASILANE
BIERNBAUM, M
WEST, R
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 131 (02) : 179 - 188
[2] BOCK H, 1978, Z NATURFORSCH B, V33
[3] BOCK H, 1978, CHEM BER, V111
[4] AN ANALYSIS OF EXCESS CHARGE EFFECT IN ALTERNANT CONJUGATED HYDROCARBON RADICAL-IONS
BOLTON, JR
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1967, 71 (11) : 3702 - &
[5] CYCLIC POLYSILANES .4. ANION RADICALS AND SPECTROSCOPIC PROPERTIES OF PERMETHYLCYCLOPOLYSILANES
CARBERRY, E
WEST, R
GLASS, GE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (20) : 5446 - &
[6] ESR-METRICS ON RADICAL ANIONS OF TRIMETHYLSILYL SUBSTITUTED PI-ELECTRON SYSTEMS
GERSON, F
HEINZER, J
BOCK, H
ALT, H
SEIDL, H
[J]. HELVETICA CHIMICA ACTA, 1968, 51 (04) : 707 - &
[7] ORGANIC SUBSTITUTED CYCLOSILANES
GILMAN, H
SCHWEBKE, GL
[J]. ADVANCES IN ORGANOMETALLIC CHEMISTRY, 1964, 1 : 89 - 141
[8] ANION RADICALS OF PHENYLSILANES
WAN, YP
SMENTOWS.FJ
OBRIEN, DH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (22) : 7680 - &
[9] PERMETHYLPOLYSILANES - SILICON ANALOGS OF HYDROCARBONS
WEST, R
CARBERRY, E
[J]. SCIENCE, 1975, 189 (4198) : 179 - 186

← 1 →