THE INFLUENCE OF THE SPIN ORBIT AND THE HYPERFINE INTERACTION ON THE ASYMPTOTIC-BEHAVIOR OF THE A-1-SIGMA-U+ STATE OF NA2

被引：32

作者：

KNOCKEL, H

JOHR, T

RICHTER, H

TIEMANN, E

机构：

[1] Institut für Atom- und Molekülphysik, Universität Hannover, W-3000 Hannover 1

来源：

CHEMICAL PHYSICS | 1991年 / 152卷 / 03期

关键词：

D O I：

10.1016/0301-0104(91)85014-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The vibrational structure of the A 1-SIGMA-u+ excited state of Na2 has been investigated using a molecular beam experiment. Vibrational levels with quantum numbers up to 184 have been accessed. The highest is about 0.025 cm-1 below the dissociation limit and its outer turning point corresponds to a separation of the two atoms of about 200 angstrom. A more precise dissociation energy of 22978.21 (10) cm-1 with respect to the minimum of the ground state is derived. The spin-orbit and the hyperfine interaction split the manifold of the atomic asymptote Na(S-2) + Na(P-2). Their influence on the asymptotic behaviour of the A 1-SIGMA-u+ state of Na2 is qualitatively discussed.

引用

页码：399 / 407

页数：9

共 25 条

[1] LASER-ABSORPTION SPECTROSCOPY OF THE A1-SIGMA-U+-X1-SIGMA-G+(V',V'')-BANDS OF NA-2 [J].