ELECTRO-OPTICAL MULTICHANNEL SPECTROMETER FOR TRANSIENT RESONANCE RAMAN AND ABSORPTION SPECTROSCOPY

An optical multichannel system is described, used for time-dependent absorption measurements in the gas phase and the liquid phase and for resonance Raman spectroscopy of short-lived transient species in the liquid phase in pulse radiolysis. It consists of either an image converter streak unit or an image intensifier coupled to a TV camera with computerized data handling. The system enables the recording of time-dependent absorption spectra or resonance Raman spectra of short-lived radicals and excited states with single electron and light pulses.