A PENTAVALENT W4S4 CUBOIDAL CLUSTER

被引：10

作者：

SAMPSON, ML ^{[1
]}

RICHARDSON, JF ^{[1
]}

NOBLE, ME ^{[1
]}

机构：

[1] UNIV LOUISVILLE,DEPT CHEM,LOUISVILLE,KY 40292

来源：

INORGANIC CHEMISTRY | 1992年 / 31卷 / 13期

关键词：

D O I：

10.1021/ic00039a013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The W(V) complex [W(NC6H4CH3)(S2P(OC2H5)2)(mu-3-S)]4 was prepared and characterized. The compound, in solution, is engaged in an associative equilibrium from two dimers, with K(eq) = 1600 M-1. When this compound is in solution with [Mo-(NC6H4CH3)(S2P(OC2H5)2)(mu-3-S)]4, the mixed-metal cluster [W2Mo2(NC6H4CH3)4(S2P(OC2H5)2)4(mu-3-S)4] is formed. The crystal structure of [W(NC6H4CH3)(S2P(OC2H5)2)(mu-3-S)]4 was determined: a = 14.650 (3) angstrom, b = 19.133 (4) angstrom, c = 13.073 (3) angstrom, alpha = 101.82 (2)-degrees, beta = 104.61 (2)-degrees, gamma = 75.92 (2)-degrees; triclinic; P1BAR; Z = 2. The crystallography showed a distorted W4S4 cubic arrangement.

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页码：2726 / 2730

页数：5

相关论文

共 61 条

[1]

[Anonymous], 1974, INT TABLES XRAY CRYS, VIV

[2] SULFUR MEDIATED INDUCED ELECTRON-TRANSFER REACTIONS IN W-S SYSTEMS - SYNTHESIS AND REACTIVITY OF (ET4N)2[W2(V)O2(MU-S)2(S2)2] [J].

ANSARI, MA ;

CHANDRASEKARAN, J ;

SARKAR, S .

POLYHEDRON, 1988, 7 (06) :471-476

[3] ORGANOIMIDO-COMPLEXES OF TUNGSTEN-(VI) TUNGSTEN-(V), AND TUNGSTEN-(IV) - CRYSTAL AND MOLECULAR-STRUCTURES OF [W(NPH)CL3(PPH3)2] AND [W(NPH)CL2(PME3)3] [J].

BRADLEY, DC ;

HURSTHOUSE, MB ;

MALIK, KMA ;

NIELSON, AJ ;

SHORT, RL .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (12) :2651-2656

[4] SYNTHESIS AND CHARACTERIZATION OF BINUCLEAR AND TRINUCLEAR ORGANOIMIDO COMPLEXES OF TUNGSTEN-(VI) AND TUNGSTEN-(V) AND A BINUCLEAR TUNGSTEN(V) OXOANION - X-RAY CRYSTAL-STRUCTURES OF [(WCI4(NET))2], [P(CH2PH)PH3][W3CL7(NBUT)3-(MU-NPH)3], [P(CH2PH)PH3][W2CL7(NR)2] (R = ET OR PH), AND [P(CH2PH)PH3]- [W2O2CL7] [J].

BRADLEY, DC ;

ERRINGTON, RJ ;

HURSTHOUSE, MB ;

SHORT, RL .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (03) :1043-1051

[5] MONO(PHOSPHINE), BIS(PHOSPHINE), AND TRIS(PHOSPHINE) DERIVATIVES OF MU-3-SULFIDO HYDRIDO COMPLEXES OF RHODIUM AND IRIDIUM - SYNTHESES AND X-RAY CRYSTAL-STRUCTURES OF 50-ELECTRON RH3(H)(MU-3S)2(1,5-CYCLOOCTADIENE)2(PME3)3 AND IR3(H)(MU-3-S)2(1,5-CYCLOOCTADIENE)3(PME3) AND 48-ELECTRON IR3(H)(MU-3-S)2(1,5-CYCLOOCTADIENE)2(TERT-BU2PH)2 [J].

BRIGHT, TA ;

JONES, RA ;

KOSCHMIEDER, SU ;

NUNN, CM .

INORGANIC CHEMISTRY, 1988, 27 (21) :3819-3825

[6] THE REACTION OF THE SULFUR-RICH COMPOUNDS (C5ME5)2MO2S4 AND (C5ME5)2CR2S5 WITH M-M DOUBLE BONDING OF THE COMPLEX [ETA-5-C5R5(CO)2M']2 (R=H,CH3 AND M'=CR,MO,W) AND 2-NUCLEAR AND 3-NUCLEAR CLUSTERS WITH M3S4 AND M4S4 STRUCTURES [J].

BRUNNER, H ;

KAUERMANN, H ;

WACHTER, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1984, 265 (02) :189-198

[7] MOLYBDENUM ENZYMES, COFACTORS, AND MODEL SYSTEMS - THE CHEMICAL UNIQUENESS OF MOLYBDENUM [J].

BURGMAYER, SJN ;

STIEFEL, EI .

JOURNAL OF CHEMICAL EDUCATION, 1985, 62 (11) :943-953

[8]

CHICHANG L, 1990, JIEGOU HUAXUE, V9, P111

[9] INSERTION OF [VFE3S4]2+ AND [MOFE3S4]3+ CORES INTO A SEMIRIGID TRITHIOLATE CAVITAND LIGAND - REGIOSPECIFIC REACTIONS AT A VANADIUM SITE SIMILAR TO THAT IN NITROGENASE [J].

CIURLI, S ;

HOLM, RH .

INORGANIC CHEMISTRY, 1989, 28 (09) :1685-1690

[10] DINUCLEAR TUNGSTEN(V) AND MOLYBDENUM(V) COMPOUNDS CONTAINING M2S2(MU-S)22+ CORES - SYNTHESIS AND REACTIVITY OF [N(C2H5)4]2M2S12 (M = W OR MO) AND THE CRYSTAL-STRUCTURE OF [N(C2H5)4]2W2S2(MU-S)2(S4)2 [J].

COHEN, SA ;

STIEFEL, EI .

INORGANIC CHEMISTRY, 1985, 24 (26) :4657-4662

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