PHOTOCHROMIC HETEROCYCLIC FULGIDES .7. (E)-ADAMANTYLIDENE-[1-(2,5-DIMETHYL-3-FURYL)ETHYLIDENE]SUCCINIC ANHYDRIDE AND DERIVATIVES - MODEL PHOTOCHROMIC COMPOUNDS FOR OPTICAL-RECORDING MEDIA

被引：46

作者：

GLAZE, AP ^{[1
]}

HELLER, HG ^{[1
]}

WHITTALL, J ^{[1
]}

机构：

[1] UNIV WALES COLL CARDIFF,SCH CHEM & APPL CHEM,POB 912,CARDIFF CF1 3TB,WALES

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1992年 / 04期

关键词：

D O I：

10.1039/p29920000591

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The thermally-stable coloured form 5a, obtained by irradiation (lambda = 366 nm) of the title compound 4a, contains a rigid inflexible spiroadamantylidene group which results in a five- to nine-fold increase in the quantum efficiency for bleaching compared to the analogous compound 2 having methyl groups in the 7-position. The quantum efficiency for bleaching decreases with increasing wavelength of irradiation and increases with increasing temperature in a linear manner, and is solvent dependent.

引用

页码：591 / 594

页数：4

共 6 条

[1]

AMREIN W, 1974, CHIMIA, V28, P185

[2] PHOTOCHROMIC HETEROCYCLIC FULGIDES .2. ELECTROCYCLIC REACTIONS OF (E)-ALPHA-2,5-DIMETHYL-3-FURYLETHYLIDENE(ALKYL-SUBSTITUTED METHYLENE)-SUCCINIC ANHYDRIDES [J].

DARCY, PJ ;

HELLER, HG ;

STRYDOM, PJ ;

WHITTALL, J .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1981, (01) :202-205

[3] CALCULATION OF PHOTOSTATIONARY STATES IN SYSTEMS A[]B WHEN ONLY A IS KNOWN [J].

FISCHER, E .

JOURNAL OF PHYSICAL CHEMISTRY, 1967, 71 (11) :3704-&

[4] PHOTOCHROMIC HETEROCYCLIC FULGIDES .3. THE USE OF (E)-ALPHA-(2,5-DIMETHYL-3-FURYLETHYLIDENE) (ISOPROPYLIDENE)SUCCINIC ANHYDRIDE AS A SIMPLE CONVENIENT CHEMICAL ACTINOMETER [J].

HELLER, HG ;

LANGAN, JR .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1981, (02) :341-343

[5] REVERSIBLE FORMATION AND ERADICATION OF COLORS BY IRRADIATION AT LOW TEMPERATURES - A PHOTOCHEMICAL MEMORY MODEL [J].

HIRSHBERG, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (10) :2304-2312

[6]

STIMPSON SL, 1990, THESIS U WALES COLLE

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