BIOMIMETIC SYNTHESIS OF AGELASIDINE-A

被引：16

作者：

ICHIKAWA, Y

KASHIWAGI, T

URANO, N

机构：

[1] Faculty of Education, Mie University, Tsu, 514

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1992年 / 12期

关键词：

D O I：

10.1039/p19920001497

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Agelasidine A 1 was synthesized using the [2,3]sigmatropic rearrangement of an allylic sulfinate to an allylic sulfone at low concentration. This biomimetic approach provided an efficient three-step synthesis of agelasidine A 1 from farnesol 16 in 54% overall yield.

引用

页码：1497 / 1500

页数：4

共 13 条

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