[1] Faculty of Education, Mie University, Tsu, 514
来源:
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
|
1992年
/
12期
关键词:
D O I:
10.1039/p19920001497
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
Agelasidine A 1 was synthesized using the [2,3]sigmatropic rearrangement of an allylic sulfinate to an allylic sulfone at low concentration. This biomimetic approach provided an efficient three-step synthesis of agelasidine A 1 from farnesol 16 in 54% overall yield.