BIOMIMETIC SYNTHESIS OF AGELASIDINE-A

被引:16
作者
ICHIKAWA, Y
KASHIWAGI, T
URANO, N
机构
[1] Faculty of Education, Mie University, Tsu, 514
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1992年 / 12期
关键词
D O I
10.1039/p19920001497
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Agelasidine A 1 was synthesized using the [2,3]sigmatropic rearrangement of an allylic sulfinate to an allylic sulfone at low concentration. This biomimetic approach provided an efficient three-step synthesis of agelasidine A 1 from farnesol 16 in 54% overall yield.
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页码:1497 / 1500
页数:4
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