SYNTHESIS OF OPTICALLY-ACTIVE ALPHA-METHYLENE-GAMMA-BUTYROLACTONES AND (+)-MINTLACTONE

被引：26

作者：

CRISP, GT

MEYER, AG

机构：

[1] Department of Chemistry, University of Adelaide, Adelaide

来源：

TETRAHEDRON | 1995年 / 51卷 / 20期

关键词：

D O I：

10.1016/0040-4020(95)00236-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The combination of baker's yeast reductions of beta-keto carbonyls, vinyl triflate formation and a palladium-catalysed, intramolecular, carbonylative coupling affords optically active a-methylene gamma-butyrolactones. The synthesis of the unnatural (+)mintlactone using this methodology is also described.

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页码：5831 / 5846

页数：16

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