CYCLOPROPANATION AND EPOXIDATION OF 1,2-DISTANNYLALKENES AND 1-SILYL-2-STANNYLALKENES

被引：7

作者：

MITCHELL, TN

KOWALL, B

机构：

[1] Fachbereich Chemie, Universität Dortmund

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 490卷 / 1-2期

关键词：

TIN; SILICON; CYCLOPROPANATION; EPOXIDATION;

D O I：

10.1016/0022-328X(94)05245-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cyclopropanation of the title compounds is possible under certain conditions (CH2I2-Sm (Hg)) in special cases, but epoxidation is apparently a general reaction which occurs readily in a stereospecific manner when they are treated with m-chloroperbenzoic acid.

引用

页码：239 / 242

页数：4

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