INTERCALATION AND POLYMERIZATION OF 4-ANILINOANILINE AND 4-ANILINOANILINIUM IODIDE IN THE VOPO4 AND V2O5 INTERLAYER SPACES

被引：31

作者：

NAKAJIMA, H

MATSUBAYASHI, GE

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Osaka University, Toyonaka, Osaka 560

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1995年 / 5卷 / 01期

关键词：

D O I：

10.1039/jm9950500105

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Reactions of 4-anilinoaniline and 4-anilinoanilinium iodide with powdered VOPO4.2H(2)O suspended in ethanol gave compounds intercalated with the 4-anilinoanilinium cation. Reactions of 4-anilinoaniline and its hydrogen iodide salt with powdered V2O5.nH(2)O suspended in ethanol resulted in the direct oxidative polymerization of 4-anilinoanilinium moieties in the V2O5 interlayer space. The polymerization processes of 4-anilinoaniline and its hydrogen iodide salt in the VOPO4 and V2O5 interlayer spaces are discussed on the basis of powder X-ray diffraction patterns, infrared and X-ray photoelectron spectroscopies as well as gel-permeation chromatography.

引用

页码：105 / 108

页数：4

共 32 条

[1] INTERCALATION OF METALLICINIUM IONS IN V2O5 GELS [J].