NETWORK, STRUCTURE OF INORGANIC-ORGANIC HYBRID GELS

被引:5
作者
KAJIWARA, K [1 ]
KRAKOVSKY, I [1 ]
URAKAWA, H [1 ]
KOHJIYA, S [1 ]
机构
[1] KYOTO UNIV, CHEM RES INST, UJI, KYOTO 611, JAPAN
关键词
D O I
10.1002/masy.19950930105
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Two series of inorganic/organic hybrid gels were prepared by the sol-gel reaction of triethoxysilyl-terminated poly(tetramethylene oxide) and tetraethoxysilane. The structure of hybrid gels was observed by small-angle X-ray scattering, and the scattered profiles were analysed by assuming a priori the density correlation functions. The results suggest that the hybrid gel is composed of organic-rich, inorganic-rich and organic/inorganic mixed regions. The size and structure of respective regions were discussed in terms of the correlation lengths evaluated from the scattering profiles.
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页码:11 / 16
页数:6
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