SELF-COLLISIONAL COUPLING AND BROADENING IN THE ASYMMETRIC ROTOR CHF2CL

被引：17

作者：

CAZZOLI, G ^{[1
]}

CLUDI, L ^{[1
]}

COTTI, G ^{[1
]}

ESPOSTI, CD ^{[1
]}

BUFFA, G ^{[1
]}

TARRINI, O ^{[1
]}

机构：

[1] UNIV PISA,DIPARTIMENTO FIS,I-56126 PISA,ITALY

来源：

JOURNAL OF CHEMICAL PHYSICS | 1995年 / 102卷 / 03期

关键词：

D O I：

10.1063/1.469173

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The line shape of 15 selected CHF2Cl rotational transitions is studied in the 59-1049 GHz frequency region. Collisional broadening parameters are measured and compared to semiclassical calculations. For some pairs of lines a large collisional coupling effect is observed and analyzed. A semiclassical theoretical model is presented allowing calculations of the coupling parameters in good agreement with measurements. © 1995 American Institute of Physics.

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页码：1149 / 1156

页数：8

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