STUDIES ON MIXED CHELATES .9. NEW MIXED NICKEL(II) CHELATE WHICH ASSUMES 4-COORDINATE,5-COORDINATE, AND 6-COORDINATE STRUCTURES IN VARIOUS ORGANIC-SOLVENTS

被引：10

作者：

HOSHINO, N ^{[1
]}

FUKUDA, Y ^{[1
]}

SONE, K ^{[1
]}

机构：

[1] OCHANOMIZU UNIV,FAC SCI,DEPT CHEM,BUNKYO KU,TOKYO 112,JAPAN

来源：

TRANSITION METAL CHEMISTRY | 1979年 / 4卷 / 03期

关键词：

D O I：

10.1007/BF00619064

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new mixed nickel(II) chelate, Ni(tmen)(acac)(NCS) · 0-1 H2O, was prepared. It was found that this (anhydrous) chelate changes from a 6-coordinate, probably dimeric structure in the solid state to (i) a 5-coordinate square pyramidal, (ii) a 4-coordinate square planar and (iii) 6-coordinate solvated structure, according to the solvent used. © 1979 Verlag Chemie, GmbH.

引用

页码：183 / 186

页数：4

共 11 条

[1] STUDIES ON MIXED CHELATES .2. MIXED NICKEL(II) CHELATES WITH N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE AND BETA-DIKETONES[1] [J].

FUKUDA, Y ;

SONE, K .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1972, 34 (07) :2315-&

[2] STUDIES ON MIXED CHELATES .4. INFLUENCE OF ALPHA-SUBSTITUENT GROUPS IN BETA-DIKETONES ON STRUCTURE OF THEIR MIXED NICKEL(II) CHELATES WITH N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE [J].

FUKUDA, Y ;

SONE, K .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1975, 37 (02) :455-460

[3] STUDIES ON MIXED CHELATES .5. MIXED NICKEL(II) CHELATES WITH "N,N,N',N'-TETRAETHYLETHYLENEDIAMINE AND BETA-DIKETONES [J].

FUKUDA, Y ;

MORISHITA, R ;

SONE, K .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1976, 49 (04) :1017-1022

[4] USE OF CONDUCTIVITY MEASUREMENTS IN ORGANIC SOLVENTS FOR CHARACTERISATION OF COORDINATION COMPOUNDS [J].

GEARY, WJ .

COORDINATION CHEMISTRY REVIEWS, 1971, 7 (01) :81-&

[5]

GUTMANN V, 1975, Z ANORG ALLG CHEM, V412, P168

[6]

GUTMANN V, 1968, COORDINATION CHEM NO, P19

[7]

GUTMANN V, 1972, NONAQUEOUS CHEM, P75

[8] THERMOCHROMISM OF ORGANIC SOLUTIONS OF N,N'-BIS-(3-AMINOPROPYL)PIPERAZINE NICKEL-COMPLEXES [J].

IWASAKI, N ;

SONE, K ;

FUKUDA, Y .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1975, 412 (02) :170-178

[9]

Nakamoto K., 1978, INFRARED RAMAN SPECT, p[270, 346]

[10]

NGA NT, 1977, B CHEM SOC JPN, V50, P154

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