DI-(2,2,2-TRICHLOROETHYL)-CARBONATE - BY-PRODUCT IN REACTIONS WITH 2,2,2-TRICHLOROETHYL CHLOROFORMATE

被引：9

作者：

HE, XS ^{[1
]}

BROSSI, A ^{[1
]}

机构：

[1] NIDDKD, NAT PROD SECT, STRUCT BIOL LAB, BETHESDA, MD 20892 USA

来源：

SYNTHETIC COMMUNICATIONS | 1990年 / 20卷 / 14期

关键词：

D O I：

10.1080/00397919008053155

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2,2,2-Trichloroethyl chloroformate (1) in higher boiling solvents, particularly in the presence of potassium carbonate and potassium bicarbonate, affords undesired di-(2,2,2-trichloroethyl)-carbonate (2) as a byproduct. When chemically pure chloroformate was used, addition of carbonates was found to be unnecessary in N-demethylation reactions. © 1990, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：2177 / 2179

页数：3

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