SOLVENT EFFECT OF AMINES ON THE CLAISEN REARRANGEMENT OF ALLYL [ORTHO-SUBSTITUTED OR PARA-SUBSTITUTED PHENYL] ETHERS

被引：2

作者：

GOTO, M

HAYASHI, T

机构：

[1] Department of Chemistry, Faculty of Science and Engineering, Ritsumeikan University, Kita~ku

来源：

NIPPON KAGAKU KAISHI | 1979年 / 06期

关键词：

D O I：

10.1246/nikkashi.1979.743

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Claisen rearrangement of allyl [o(or p) -substituted phenyl] ethers was carried out in the presence of various solvents, and effect of the solvent on the rate of the rearrangement was investigated. No correlation was found between electron donating ability or basicity of solvents and the rate of the rearrangement. The rate acceleration effect obtained in the presence of aniline derivatives as a solvent was found to be proportional mainly to the sum of the dipole moment and hydrogen bonding ability of the solvents. © 1979, The Chemical Society of Japan. All rights reserved.

引用

页码：743 / 747

页数：5

共 8 条

[1] THE VARIATION OF DIPOLE MOMENT WITH STATE FOR NORMAL-PROPYL-AMINES AND NORMAL-BUTYL-AMINES - WITH NOTES ON THE APPARENT MOMENTS IN SOLUTION OF CERTAIN OTHER AMINES [J].