MOLECULAR RECOGNITION OF ANIONIC SUBSTRATES - BINDING OF CARBOXYLATES BY A MACROBICYCLIC CORECEPTOR AND CRYSTAL-STRUCTURE OF ITS SUPRAMOLECULAR CRYPTATE WITH THE TEREPHTHALATE DIANION

被引：99

作者：

LEHN, JM ^{[1
]}

MERIC, R ^{[1
]}

VIGNERON, JP ^{[1
]}

BKOUCHEWAKSMAN, I ^{[1
]}

PASCARD, C ^{[1
]}

机构：

[1] CNRS,INST CHIM SUBST NAT,CRISTALLOCHIM LAB,F-91190 GIF SUR YVETTE,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 02期

关键词：

D O I：

10.1039/c39910000062

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The macrobicyclic polyammonium receptor molecule 1-6H+ binds dicarboxylate substrates with linear recognition and forms with terephthalate a very stable dianion cryptate the crystal structure of which has been determined.

引用

页码：62 / 64

页数：3

共 13 条

[1] MOLECULAR RECOGNITION IN ANION COORDINATION CHEMISTRY - STRUCTURE, BINDING CONSTANTS AND RECEPTOR-SUBSTRATE COMPLEMENTARITY OF A SERIES OF ANION CRYPTATES OF A MACROBICYCLIC RECEPTOR MOLECULE [J].

DIETRICH, B ;

GUILHEM, J ;

LEHN, JM ;

PASCARD, C ;

SONVEAUX, E .

HELVETICA CHIMICA ACTA, 1984, 67 (01) :91-104

[2] ANION RECEPTOR MOLECULES - CHAIN-LENGTH DEPENDENT SELECTIVE BINDING OF ORGANIC AND BIOLOGICAL DICARBOXYLATE ANIONS BY DITOPIC POLYAMMONIUM MACROCYCLES [J].

HOSSEINI, MW ;

LEHN, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (12) :3525-3527

[3] ANION CORECEPTOR MOLECULES - LINEAR MOLECULAR RECOGNITION IN THE SELECTIVE BINDING OF DICARBOXYLATE SUBSTRATES BY DITOPIC POLYAMMONIUM MACROCYCLES [J].

HOSSEINI, MW ;

LEHN, JM .

HELVETICA CHIMICA ACTA, 1986, 69 (03) :587-603

[4] POLYAZA MACROBICYCLIC CRYPTANDS - SYNTHESIS, CRYSTAL-STRUCTURES OF A CYCLOPHANE TYPE MACROBICYCLIC CRYPTAND AND OF ITS DINUCLEAR COPPER(I) CRYPTATE, AND ANION BINDING FEATURES [J].

JAZWINSKI, J ;

LEHN, JM ;

LILIENBAUM, D ;

ZIESSEL, R ;

GUILHEM, J ;

PASCARD, C .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (22) :1691-1694

[5] SUPRAMOLECULAR CHEMISTRY - SCOPE AND PERSPECTIVES MOLECULES, SUPERMOLECULES, AND MOLECULAR DEVICES [J].

LEHN, JM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1988, 27 (01) :89-112

[6] MOLECULAR RECOGNITION - ANION CRYPTATES OF A MACROBICYCLIC RECEPTOR MOLECULE FOR LINEAR TRIATOMIC SPECIES [J].

LEHN, JM ;

SONVEAUX, E ;

WILLARD, AK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (15) :4914-4916

[7] SUPRAMOLECULAR CHEMISTRY - RECEPTORS, CATALYSTS, AND CARRIERS [J].

LEHN, JM .

SCIENCE, 1985, 227 (4689) :849-856

[8]

PASCARD C, 1982, J CHEM SOC CHEM COMM, P527

[9]

PIERRE JL, 1983, B SOC CHIM FR, V2, P367

[10]

SCHMIDTCHEN FP, 1986, TOP CURR CHEM, V132, P101

← 1 2 →