SYNTHESIS AND CHEMISTRY OF 2,5-DIMETHYLENE-2,5-DIHYDROFURAN

被引：11

作者：

CHEN, PS

CHOU, CH

机构：

[1] Department of Chemistry, National Sun Yat-Sen University, Kaohsiung

来源：

JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 1992年 / 39卷 / 03期

关键词：

2,5-DIMETHYLENE-2,5-DIHYDROFURAN; FLASH VACUUM PYROLYSIS;

D O I：

10.1002/jccs.199200043

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2,5-Dimethylene-2,5-dihydrofuran (3), generated flash pyrolitically, underwent di- and trimerization reactions to give cyclic dimer and trimer. Compound 3 was trapped with methanol, ethanol, bromine, acetic acid, thiophenol and oxygen. Results from trapping experiments suggest that the diradical form of 3 is involved.

引用

收藏

页码：251 / 255

页数：5

相关论文

共 17 条

[1] THE CHEMISTRY OF XYLYLENES .3. SOME REACTIONS OF RHO-XYLYLENE THAT OCCUR BY FREE RADICAL INTERMEDIATES [J].

ERREDE, LA ;

HOYT, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (02) :436-439

[2] THE CHEMISTRY OF PARA-XYLYLENE .1. THE PREPARATION OF SOLUTIONS OF PSEUDODIRADICALS [J].

ERREDE, LA ;

LANDRUM, BF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (18) :4952-4955

[3] THE CHEMISTRY OF PARA-XYLYLENE .2. THE REACTION OF PARA-XYLYLENE WITH OXYGEN [J].

ERREDE, LA ;

HOPWOOD, SL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (24) :6507-6510

[4] THE CHEMISTRY OF XYLYLENES .6. THE POLYMERIZATION OF PARA-XYLYLENE [J].

ERREDE, LA ;

GREGORIAN, RS ;

HOYT, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (19) :5218-5223

[5]

FIESER LF, 1967, REAGENTS ORGANIC SYN, V1, P584

[6]

HUANG CS, 1991, THESIS NATIONAL YS S

[7] FLUORIDE-INDUCED 1,6-ELIMINATION TO P-QUINODIMETHANE - A NEW PREPARATIVE METHOD FOR [2.2]PARACYCLOPHANE, [2.2](2.5)FURANOPHANE AND [2.2](2.5)THIOPHENOPHANE [J].

ITO, Y ;

MIYATA, S ;

NAKATSUKA, M ;

SAEGUSA, T .

JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (05) :1043-1044

[8] [6+6] PHOTOCLEAVAGE OF [2.2]CYCLOPHANES [J].

KAUPP, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1976, 15 (07) :442-443

[9] ORTHO-XYLYLENES AND ISOINDENES AS REACTION INTERMEDIATES [J].

MCCULLOUGH, JJ .

ACCOUNTS OF CHEMICAL RESEARCH, 1980, 13 (08) :270-276

[10] DETECTION OF 2,5-DIMETHYLENE-2,5-DIHYDROTHIOPHENE AND THIOPHENORADIALENE [J].

MUNZEL, N ;

KESPER, K ;

SCHWEIG, A ;

SPECHT, H .

TETRAHEDRON LETTERS, 1988, 29 (48) :6239-6242