SOLID LIQUID PHASE-TRANSFER CATALYSIS WITHOUT SOLVENT - SELECTIVE MONOALKYLATION AND DIALKYLATION OF BENZYL METHYL KETONE

被引：16

作者：

ARANDA, A ^{[1
]}

DIAZ, A ^{[1
]}

DIEZBARRA, E ^{[1
]}

DELAHOZ, A ^{[1
]}

MORENO, A ^{[1
]}

SANCHEZVERDU, P ^{[1
]}

机构：

[1] UNIV CASTILLA LA MANCHA,FAC QUIM,E-13071 CIUDAD REAL,SPAIN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1992年 / 18期

关键词：

D O I：

10.1039/p19920002427

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The alkylation of benzyl methyl ketone 1 has been performed by phase-transfer catalysis without solvent. Excellent yields of mono- 2 and di-alkyl derivatives 3 and 4 were obtained through general, selective and mild conditions.

引用

页码：2427 / 2430

页数：4

共 17 条

[1] DIRECT ALKYLATION OF KETONES AND ALDEHYDES IN THE PRESENCE OF SOLID POTASSIUM IN SUSPENSION
ARTAUD, I
TOROSSIAN, G
VIOUT, P
[J]. TETRAHEDRON, 1985, 41 (21) : 5031 - 5037
[2] BRANDSTROM A, 1972, TETRAHEDRON LETT, P473
[3] Cain D., 1979, CARBON CARBON BOND F, V1, P85
[4] DEHMLOW EV, 1983, PHASE TRANSFER CATAL, P141
[5] PHASE-TRANSFER CATALYSIS WITHOUT SOLVENT - USE OF ALKYL IODIDES
DIEZBARRA, E
DELAHOZ, A
SANCHEZMIGALLON, A
SANCHEZVERDU, P
BRAM, G
LOUPY, A
PEDOUSSAUT, M
PIGEON, P
[J]. SYNTHETIC COMMUNICATIONS, 1989, 19 (1-2) : 293 - 296
[6] PHASE-TRANSFER CATALYSIS WITHOUT SOLVENT - SELECTIVE MONOALKYLATION OR DIALKYLATION OF MALONONITRILE
DIEZBARRA, E
DELAHOZ, A
MORENO, A
SANCHEZVERDU, P
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1991, (10): : 2589 - 2592
[7] FORNASIER R, 1976, TETRAHEDRON LETT, P1381
[8] POLYSULFOXIDES AS NEW TYPE OF PHASE-TRANSFER CATALYSTS IN 2 PHASE ALKYLATION
FURUKAWA, N
IMAOKA, K
FUJIHARA, H
OAE, S
[J]. CHEMISTRY LETTERS, 1982, (09) : 1421 - 1424
[9] FURUKAWA N, 1982, HETEROCYCLES, V19, P2041
[10] House H. O., 1972, MODERN SYNTHETIC REA

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