A CONVENIENT METHOD FOR THE PREPARATION OF 3-(2-PYRIDYL)TRIAZOLO[1,5-A]PYRIDINE-(L) - CRYSTAL-STRUCTURES OF L AND [CUL(2)(OH2)(2)][NO3](2)

被引：46

作者：

BATTAGLIA, LP ^{[1
]}

CARCELLI, M ^{[1
]}

FERRARO, F ^{[1
]}

MAVILLA, L ^{[1
]}

PELIZZI, C ^{[1
]}

PELIZZI, G ^{[1
]}

机构：

[1] UNIV FLORENCE,DIPARTIMENTO CHIM,I-50144 FLORENCE,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 18期

关键词：

D O I：

10.1039/dt9940002651

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compound 3-(2-pyridyl)triazolo[1,5-a]pyridine (L) was synthesized under mild conditions by refluxing equimolar amounts of hydrazine and di-2-pyridyl ketone in methanol-water. It has been characterized by X-ray diffraction and used as a ligand in two metal complexes, [ML(2)(OH2)(2)][NO3](2) (M = Cu or Co). The crystal structure of the copper derivative, which is the first example of a triazolopyridine complex, has also been determined.

引用

页码：2651 / 2654

页数：4

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