ULTRASONIC VACUUM EXTRACTION OF GASES FROM WATER FOR CHEMICAL AND ISOTOPIC ANALYSIS

被引:18
作者
HOLT, BD
STURCHIO, NC
AREHART, GB
BAKEL, AJ
机构
关键词
D O I
10.1016/0009-2541(95)00036-L
中图分类号
P3 [地球物理学]; P59 [地球化学];
学科分类号
0708 ; 070902 ;
摘要
A method is described for ultrasonic vacuum extraction of gases from groundwater samples. Ultrasonic vacuum extraction provides near-quantitative gas yields within 30 min, and allows on-line preparation of carbon dioxide, nitrogen and oxygen for isotopic analyses. This method eliminates uncertainties involved in correcting headspace gas analyses for solubilities and liquid-vapor isotopic fractionation. In addition to developmental data, some field results are given to demonstrate the applicability of the method to geochemical studies.
引用
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页码:275 / 284
页数:10
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共 22 条
[1]  
Coleman, Chao-Li, Riley, Microbial methane in the shallow Paleozoic sediments and glacial deposits of Illinois, U.S.A., Origins of Methane in the Earth, 71, pp. 23-40, (1988)
[2]  
Emerson, Quay, Stump, Wilbur, Knox, O<sub>2</sub>, Ar, N<sub>2</sub> and <sup>222</sup>Rn in surface waters of the subarctic ocean: net biological O<sub>2</sub> production, Global Biogeochemical Cycles, 5, pp. 49-64, (1991)
[3]  
Evans, Kling, Tuttle, Tanyileke, White, Gas buildup in Lake Nyos, Cameroon: the recharge process and its consequences, Appl. Geochem., 8, pp. 207-221, (1993)
[4]  
Faure, Principles of Isotope Geology, (1986)
[5]  
Heaton, Vogel, “Excess air” in groundwater, J. Hydrol., 50, pp. 201-216, (1981)
[6]  
Holt, Preparation of carbon dioxide from sulfates, sulfur dioxide, air, and water for determination of oxygen isotope ratio, Anal. Chem., 49, pp. 1664-1667, (1977)
[7]  
Holt, Kumar, Method for determination of oxygen-18 of hydrogen peroxide in rainwater, Anal. Chem., 59, pp. 995-999, (1987)
[8]  
Horibe, Shigehara, Takakuwa, Isotope separation factor of carbon dioxide-water system and isotopic composition of atmospheric oxygen, Journal of Geophysical Research, 78, pp. 2625-2629, (1973)
[9]  
Kennedy, Reynolds, Smith, Noble gas geochemistry of thermal springs, Geochim. Cosmochim. Acta, 52, pp. 1919-1928, (1988)
[10]  
Kroopnick, Craig, Atmospheric oxygen: Isotopic composition and solubility fractionation, Science, 175, pp. 54-55, (1972)