SITE SYMMETRY AND CORRELATION FIELD SPLITTING IN THE ADSORBATE CO2-NACL(100)

被引:39
作者
HEIDBERG, J
KAMPSHOFF, E
KUHNEMUTH, R
SCHONEKAS, O
STEIN, H
WEISS, H
机构
[1] Institut für Physikalische Chemie, Elektrochemie der Universität Hannover, D-3000 Hannover 1, Callinstrasse 3-
关键词
D O I
10.1016/0039-6028(90)90141-T
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Site symmetry and correlation field splitting in the s- and p-polarized infrared spectra of the v2 bending vibration of monolayer CO2 adsorbed on NaCl(100) were detected. Also the asymmetric v3 stretching vibration of the adsorbate was observed and shows a splitting due to the correlation field. The monolayer coverage was established by measurement of adsorption isotherms. These demonstrate a two-dimensional first order phase transition in CO2NaCl(100). © 1990.
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页码:L43 / L47
页数:5
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