SELECTIVITY IN NEAR-DIFFUSION-LIMITED REACTIONS - ISOTOPE EFFECTS IN PHOSPHORYLNITRENE INSERTION INTO C-H BONDS

被引：6

作者：

MASLAK, P

SCZEPANSKI, JJ

MINARD, RD

COLLINS, LA

机构：

[1] Department of Chemistry, The Pennsylvania State University, University Park

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 30期

关键词：

D O I：

10.1016/S0040-4039(00)97595-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In near-diffusion-limited reactions the apparent selectivity of reactive intermediates measured in intermolecular competition experiments is a function of the intrinsic selectivity and the ratio of the reaction rate to the diffusion controlled rate. This dependence can be used to test for diffusion limited reactions as demonstrated by measurements of isotope effects for CH insertion of phosphorylnitrenes. © 1990.

引用

页码：4261 / 4264

页数：4

共 12 条

[1] Biemann K, 1962, MASS SPECTROMETRY OR, P204
[2] LOSS OF THE NORMAL INTRAMOLECULAR PREFERENTIAL REACTIVITY WITH A HIGHLY NONSELECTIVE NITRENE
BRESLOW, R
HERMAN, F
SCHWABACHER, AW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (18) : 5359 - 5360
[3] BRESLOW R, 1974, J AM CHEM SOC, V96, P5937, DOI 10.1021/ja00825a042
[4] PHOTOLYSIS OF 1-AZIDOPHOSPHETAN OXIDES
HARGER, MJP
[J]. JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1971, (09): : 442 - &
[5] Koenig T., 1973, FREE RADICALS, V1, P157
[6] A SIMPLE TEST FOR DIFFUSION-LIMITED REACTIONS - NEAR-DIFFUSION-CONTROLLED NITRENE INSERTION INTO C H BONDS
MASLAK, P
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (21) : 8201 - 8207
[7] ROTATIONAL DIFFUSION CONTROL OF RADICAL DISPROPORTIONATION IN SOLID-STATE PHOTOLYSIS OF AZOBISISOBUTYRONITRILE
MCBRIDE, JM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (23) : 6302 - &
[8] POUTSMA ML, 1973, FREE RADICALS, V2, P172
[9] PREPARATION PROPERTIES + THERMAL DECOMPOSITION PRODUCTS OF ORGANOAZIDES OF SILICON GERMANIUM TIN LEAD PHOSPHORUS + SULFUR
REICHLE, WT
[J]. INORGANIC CHEMISTRY, 1964, 3 (03) : 402 - &
[10] Rice SA, 1985, CHEM KINETICS, V25

← 1 2 →