NUMERICAL HARTREE-FOCK STUDY ON THE RYDBERG-LIKE EXCITATIONS OF HE-2-

被引：13

作者：

ADAMOWICZ, L ^{[1
]}

PLUTA, T ^{[1
]}

机构：

[1] MEMPHIS STATE UNIV, DEPT CHEM, MEMPHIS, TN 38152 USA

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 179卷 / 5-6期

关键词：

D O I：

10.1016/0009-2614(91)87096-T

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two new metastable states, 4-PHI-g and 4I(g) of the He2- anion are characterized using the numerical Hartree-Fock method. It is determined that such metastable quartet states are formed when the He2+ core attracts two electrons, which are placed into bonding orbitals, whose angular momentum quantum number differs by one.

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页码：517 / 523

页数：7

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