A PREPARATION OF POTASSIUM TRIS(1,2,4-TRIAZOL-1-YL)HYDROBORATE AND OF SOME METAL DERIVATIVES

被引：21

作者：

LOBBIA, GG

BONATI, F

CECCHI, P

机构：

[1] Dipartimento di Scienze Chimiche, University di Camerino, 1-62032, Camerino, (MC)

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1991年 / 21卷 / 08期

关键词：

D O I：

10.1080/15533179108020211

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Several thermally stable ML2 and ClM'L compounds (M = Mn, Fe, Co, Ni, Cu, Zn, Cd; M' = Hg, Pb, VO) were obtained from the corresponding halide and potassium hydrotris(1,2,4-triazol-1-yl)borate, KL. While monomeric L2Zn and LPbCl are soluble in dimethyl sulphoxide, the others are insoluble coordination polymers where the ligand [L]- is exopolydentate as in the metal derivatives of a related neutral ligand, tris(1,2,4-triazol-1-yl)methane.

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页码：1141 / 1151

页数：11

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