STEREOSELECTIVE CYCLIZATION VIA ZIRCONOCENE-CATALYZED INTRAMOLECULAR OLEFIN ALLYLATION

被引：54

作者：

KNIGHT, KS ^{[1
]}

WAYMOUTH, RM ^{[1
]}

机构：

[1] STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 07期

关键词：

D O I：

10.1021/om00019a013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the presence of excess butylmagnesium chloride and in diethyl ether at 25-degrees-C, zirconocene dichloride is an effective catalyst precursor for the stereoselective cyclization of nonconjugated dienes containing a terminal alkoxide substituent. The products are carbocyclic rings containing adjacent vinyl and methyl substituents with trans stereochemistry.

引用

页码：2575 / 2577

页数：3

共 40 条

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