STABILITIES AND STRUCTURES OF C6F6-(C6F6) AND C6F6+(C6F6)

被引：34

作者：

HIRAOKA, K ^{[1
]}

MIZUSE, S ^{[1
]}

YAMABE, S ^{[1
]}

机构：

[1] NARA UNIV EDUCAT,DEPT CHEM,TAKABATAKE,NARA 630,JAPAN

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1990年 / 94卷 / 09期

关键词：

D O I：

10.1021/j100372a061

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The equilibria of clustering reactions C6F6∓ + C6F6 = C6F6∓(C6F6) were studied with a pulsed electron beam high-pressure mass spectrometer. Thermochemical stabilities of the clusters C6F6-(C6F6) and C6F6+(C6F6) were determined. It was found that the bond energy of C6F6-(C6F6) is larger than that of C6F6+(C6F6). While C6F6+(C6F6) has the site-to-site type geometry, C6F6-(C6F6) has a stack form according to the ab initio MO calculation. © 1990 American Chemical Society.

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页码：3689 / 3694

页数：6

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