INFLUENCE OF THE CHEMICAL BONDING ON THE LOW SPIN-]HIGH SPIN TRANSITION OF COBALT(III) IN OXIDES OF THE K2NIF4 TYPE

被引：11

作者：

DEMAZEAU, G

BYEON, SH

HAGENMULLER, P

CHOY, JH

机构：

[1] UNIV BORDEAUX 1,CNRS,CHIM SOLIDE LAB,351 COURS LIBERAT,F-33405 TALENCE,FRANCE

[2] SEOUL NATL UNIV,COLL NAT SCI,DEPT CHEM,SEOUL 151,SOUTH KOREA

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1992年 / 610卷 / 04期

关键词：

COBALT(III) IN OXIDE PHASES; ELECTRONIC STATES;

D O I：

10.1002/zaac.19926100115

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

It appears from a wide investigation of the LS --> HS transition of cobalt(III) based on a Slichter and Drickamer model that in an oxide lattice with K2NiF4-type structure, the influence of the cation size in C.N.9 sites is prevailing on that resulting from the competing bonds in the pervoskite-type layers.

引用

页码：91 / 98

页数：8

共 15 条

[1] NEW COMPOSITIONS WITH K2NIF4 STRUCTURE [J].