PREPARATION AND PROPERTIES OF POLY(METHYLPYRIDINE-2,5-DIYL)S

被引：11

作者：

MARUYAMA, T

ZHOU, Z

KUBOTA, K

YAMAMOTO, T

机构：

[1] TOKYO INST TECHNOL, RESOURCES UTILIZAT RES LAB, 4259 NAGATSUTA, MIDORI KU, YOKOHAMA, KANAGAWA 227, JAPAN

[2] GUNMA UNIV, FAC ENGN, KIRYU, GUNMA 376, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 04期

关键词：

D O I：

10.1246/cl.1992.643

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of poly(methylpyridine-2,5-diyl)s were synthesized by dehalogenation polycondensation of the corresponding 2,5-dibromo-methylpyridine with zerovalent nickel complexes. The polymers had molecular weight much higher than that of poly(pyridine-2,5-diyl). Poly(methylpyridine-2,5-diyl)s were converted into semiconducting material by chemical and electrochemical reduction (n-type doping).

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页码：643 / 646

页数：4

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