ADDITION OF TETRAHALODIBORANE (4) MOLECULES TO DIENES

被引：12

作者：

HAUBOLD, W

STANZL, K

机构：

[1] Institut für Anorganische Chemie der Universität Stuttgart, D-7000 Stuttgart 80

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 174卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)91497-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The additions of one mol of B2Cl4 or B2F4 to 1,3-butadiene yield 1,4-bis(dihalogenoboryl)-2-butene, X2BCH2CHCHCH2BX2. In the case of the chlorine compound a further molecule B2Cl4 can be added to the butene double bond. In the reaction of diboron tetrahalides with methyl-substituted conjugated or cumulated dienes we observed fast polymerisation of the hydrocarbons rather than addition reactions in almost all cases. The chemical and spectroscopic properties of the compounds are described. © 1979.

引用

页码：141 / 147

页数：7

共 13 条

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